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Apexazole® Polybenzimidazole PBI Resin


Apexazole® PBI is a fully aromatic heterocyclic high-performance thermoplastic polymer that, thanks to its exceptional thermodynamic properties, sets an industry‑leading benchmark for engineering plastics. With a glass transition temperature as high as 427°C, it remains non‑flammable, non‑melting, and non‑shrinkable even under severe high‑temperature combustion conditions. At the same time, it exhibits outstanding mechanical strength, excellent resistance to strong acids and bases, and superior electrical insulation, enabling it to withstand extreme service conditions that other specialty engineering plastics cannot endure. As such, it ranks among the highest‑performing specialty engineering plastics available today.

In terms of molding and processing, PBI powder can be used to produce AU‑60‑grade profiles via compression molding, offering optimal overall performance and suitable for precision machining into various structural components. Composite materials modified by blending with polyether ether ketone (PEEK) or polyetherketoneketone (PEKK) are supplied as AT‑series pellets, ideal for injection molding and extrusion. Furthermore, PBI material solutions can also be employed to fabricate hollow fiber membranes, flat‑sheet membranes, cast films, and metallic coatings.

 
 
Performance Parameters of Polybenzimidazole (PBI)
 
Thermal Performance Parameters
Performance Parameter Performance Parameter
Thermal decomposition temperature >600℃ Hot deformation temperature 435℃
Glass transition temperature 427℃ Instantaneous temperature tolerance 760℃
Maximum short-term operating temperature: 2 hours 500℃ Thermal conductivity at 23°C 0.4 W/(K·m)
Linear thermal expansion coefficient, 23–150°C 25 (10⁻⁶ 1/K) Linear thermal expansion coefficient >150°C 35 (10⁻⁶ 1/K)
UL Rating (1.5/3.0 mm) V-0 Limiting Oxygen Index 58
Weightlessness 30% weight loss at 900℃ - -

 

Mechanical Performance Parameters

Performance Parameter Performance Parameter
Tensile strength 174MPa Flexural strength 227MPa
Coefficient of friction with steel 0.27 Compressive strength 410MPa
Yield strength / Tensile strength NYP/130 (MPa) Ball indentation hardness 375MPa
Elongation at break of resin 30% Elastic modulus 6000
Fiber elongation at break 15% Density 1.3 g/cm³

 

Electrical Performance Parameters

Performance Parameter Performance Parameter
Dielectric strength 28kV/mm Dielectric constant 3.3
Body surface resistance >10*13Ω Volume resistivity >10*14Ω·cm
Conductivity at 100 Hz 0.001 Conductivity at 1 MHz 0.002
Dielectric loss tan δ – 100 Hz 0.001 - -

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